Selective Hydrolysis of Terminal Glycosidic Bond in α‐1‐Acid Glycoprotein Promoted by Keggin and Wells–Dawson Type Heteropolyacids

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Bottom-Up Elucidation of Glycosidic Bond Stereochemistry.

The lack of robust, high-throughput, and sensitive analytical strategies that can conclusively map the structure of glycans has significantly hampered progress in fundamental and applied aspects of glycoscience. Resolution of the anomeric α/β glycan linkage within oligosaccharides remains a particular challenge. Here, we show that "memory" of anomeric configuration is retained following gas-pha...

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ژورنال

عنوان ژورنال: Chemistry – A European Journal

سال: 2020

ISSN: 0947-6539,1521-3765

DOI: 10.1002/chem.202003189